I, Robot by Isaac Asimov

The book is a collection of nine short stories that revolve around the interaction of humans and robots. The stories are tied together by a framing narrative featuring a reporter interviewing a retiring robopsychologist, Dr. Susan Calvin. The stories explore the three "Laws of Robotics" and how they are interpreted and manipulated by humans and robots. Throughout the stories, the robots often end up behaving in unexpected ways due to their interpretation of these laws, leading to thought-provoking and often ironic outcomes.

The 517th greatest book of all time